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Chemical Recycling of Polyurethane Foam Waste Via Glycolysis

机译:聚氨酯泡沫废物通过糖醇的化学回收

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The purpose of the glycolysis of flexible polyurethane foams is to recover the polyol. In the process, three phases are obtained: an upper phase which contains the polyol, a bottom phase which has the subproducts of the reaction and the excess of glycol, and a third phase which is in the middle and it is formed by the polyurethane unreacted. Several factors that affect the reaction have been studied to optimize the yield of polyol obtained. These factors are the temperature of reaction, the time of reaction, the catalyst (diethanolamine, DEA) to solvent (diethylenglycol, DEG) mass ratio, and the catalyst +solvent to polyurethane mass ratio. The recovered polyol is compared to a virgin polyol by a GPC chromatogram in order to verify its quality.
机译:柔性聚氨酯泡沫糖醇分解的目的是回收多元醇。在该方法中,获得三相:含有多元醇的上相,具有反应的副产物的底相和过量的二醇,以及在中间的第三相,通过聚氨酯未反应形成。通过聚氨酯形成。已经研究了影响反应的几个因素以优化所获得的多元醇产率。这些因素是反应的温度,反应时间,催化剂(二乙醇胺,DEA)与溶剂(二甲基乙二醇,DEG)质量比,以及催化剂+溶剂与聚氨酯质量比。将回收的多元醇通过GPC色谱图进行比较,以验证其质量。

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