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RESOLVED FLUORESCENCE SPECTROSCOPY OF THE Cs_23~3Π_g→b~3Π_u TRANSITION

机译:CS_23〜3π_G→B〜3π_U过渡的已解决荧光光谱

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摘要

Perturbation facilitated Infrared-Infrared double resonance spectroscopy has been used to study the triplet states of Cs_2.The 3~3Π_g state has been observed rotationally resolved fluorescence spectra into the b~Π_u state and the perturbed A~1Σ_u~+ levels have been recorded. Molecular constants of the b~3Π__(0u)and A~1Σ_u~+ states were derived from the fluorescence spectra.
机译:扰动促进的红外 - 红外双共振光谱已经用于研究CS_2的三重态状态。已经观察到旋转地将荧光光谱分解为B〜π_U状态的3〜3π_G状态,并且已经记录了扰动A〜1σ_u〜+水平。来自荧光光谱的B〜3π__(0u)和〜1σ_u〜+状态的分子常数。

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