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Modeling Chemical Degradation of a Polymer Electrolyte Membrane and its Impact on Fuel Cell Performance

机译:高分子电解质膜的化学降解建模及其对燃料电池性能的影响

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One of the major issues of the application of low-temperature fuel cells like polymer electrolyte membrane fuel cells (PEFC) under automotive conditions is the limited durability. The decrease of performance of a cell is due to a number of physicochemical effects, like carbon-support corrosion, platinum oxidation and dissolution, Ostwald's ripening, poisoning through local adsorption of pollutants, or regarding the ionomer, mechanical and chemical degradation [1-5]. All these phenomena act at the same time during the operation of a PEMFC. This makes it difficult to estimate the impact of each of them on the reduction of cell potential over time [6], which also strongly depends on operating conditions and materials. Indeed, in some cases, the degradation of the membrane was identified to be the dominant mechanism for performance loss [7].
机译:在汽车条件下,高温燃料电池(PEFC)如高温燃料电池施用的主要问题之一是有限的耐用性。细胞的性能降低是由于碳溶液腐蚀,铂氧化和溶解,溶胀性氧化和溶解,通过局部吸附的污染物,或关于离聚物,机械和化学降解的血化,中毒[1-5 ]。所有这些现象在PEMFC的运作期间同时采取行动。这使得难以估计它们中的每一个对细胞潜力降低的影响[6],这也强烈取决于操作条件和材料。实际上,在某些情况下,鉴定了膜的降解是性能损失的主要机制[7]。

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