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Pr and Cr co-doped BiFeO_3 nanotubes: an advance multiferroic oxide material

机译:Pr和Cr共掺杂Bifeo_3纳米管:提前多体氧化物材料

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Arrays of single phase pure and Pr-Cr co-doped BiFeO_3 (BFO) nanotubes (NTs) with compositions BiFeO_3 and Bi_(0.9)Pr_(0.1)Fe_(0.9)Cr_(0.1)O_3 have been synthesized using Anodic Aluminium Oxide (AAO) template (pore diameter ~250 nm) by wet chemical liquid phase deposition technique. All the NTs show ferromagnetic nature at room temperature (RT). Better magnetic properties are observed in the co-doped BFO NTs with the value of saturation magnetization (M_s) ~ 49 memu/g, magnetization at the remanence (M_r) ~12 memu/g and coercive field (H_c) ~103 Oe. Increase of ferromagnetic signature in the co-doped BFO NTs is believed to be due to the collapse of the space-modulated spin structure. Significant increase in the dielectric characteristics in co-doped BFO NTs suggests lowering of leakage current due to the reduction of the oxygen vacancies in the structure. Strong Magnetodielectric effect (MD), expressed by [ε_Γ(H)-ε_Γ(O)]/ε_Γ(0) is observed in doped BFO NTs, where the increase of the dielectric constant is noticeable with the increase in the applied magnetic field. The co- doped BFO NTs show noticeable increase in MD effect at a lower field (1-2 kOe).
机译:用组合物BifeO_3和Bi_(0.9)PR_(0.1)FE_(0.1)CR_(0.1)CR_(0.1)o_3的单相纯和PR-CR共掺杂BIFEO_3(BFO)纳米管(NTS)已经使用阳极氧化铝(AAO )模板(孔径〜250nm)通过湿化学液相沉积技术。所有NTS在室温(RT)时显示了铁磁性。在具有饱和磁化强度(M_S)〜49 Memu / g的磁化值(M_R)〜12 Memu / g和矫顽磁场(H_C)〜103 OE的磁化下,在共掺杂BFO NT中观察到更好的磁性。相信共掺杂BFO NTS中铁磁签名的增加是由于空间调制旋转结构的崩溃。共掺杂BFO NTS中电介质特性的显着增加表明,由于结构中的氧空位的降低,漏电流降低。在掺杂的BFO NTS中观察到由ε_γ(H)-ε_γ(O)] /ε_γ(0)表示的强磁电效应(MD),其中介电常数的增加是显着的,随着所施加的磁场的增加。共掺杂的BFO NTS在下场(1-2 koe)下显着增加MD效应。

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