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PVDC Barrier Concepts for Demanding Coextrusion and Lamination Applications

机译:PVDC屏障概念,用于苛刻的共挤出和层压应用

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Copolymers of polyvinylidene chloride (PVDC), are-well known for their use in demanding barrier packaging applications to minimize the permeation of oxygen, water vapor, and odors. New die designs incorporating patented early encapsulation technology (US Patent 6,685,872, International Publication Number WO 02/06047, US Patent 4,643,927), coupled with temperature isolation technology developed by equipment suppliers, have eliminated degradation problems existing in the typical spiral mandrel dies used in the blown film process. These new die designs, coupled with new resin offerings; enable PVDC resins to be processed on large multilayer blown film dies. Multilayer films incorporating PVDC resins with higher temperature polymers such as Nylon, PP, and LLDPE in the skins are now possible. The advantage of coextruded multilayer films incorporating PVDC are that they offer, in a one step process, a combination of outstanding barrier performance, resistance to in-use conditions such as humidity and flex cracking, and specific physical properties given by the skin polymers. They represent the possibility of increasing product shelf life or down gauging the barrier material as well as reducing processing steps compared to laminated composite products. Its barrier performance being unaffected by humidity makes PVDC well suited for retort applications. In China, PVDC is widely used in retort applications as a monolayer film; and interest in incorporating PVDC in multilayer films for retort is growing.
机译:聚偏二氯乙烯(PVDC)的共聚物,众所周知,用于苛刻的屏障包装应用,以最小化氧气,水蒸气和气味的渗透。采用专利早期封装技术(美国专利6,685,872,国际公开号WO 02/06047,美国专利4,643,927),加上设备供应商开发的温度隔离技术(美国专利4,643,927)已经消除了典型的螺旋心轴模具中存在的退化问题吹膜过程。这些新的模具设计,加上新的树脂产品;使PVDC树脂能够在大型多层吹膜模具上加工。现在可以将具有较高温度聚合物如尼龙,PP和LLDPE的PVDC树脂的多层膜现在可以。共同挤出的多层膜的优点包括PVDC,它们在一个步骤过程中提供了出色的阻隔性能,耐湿度和柔性裂解的抗性,以及皮肤聚合物给出的特异性物理性质。与层压复合产品相比,它们代表了增加产品保质期或向下测量屏障材料的可能性以及减少加工步骤。它的屏障性能不受湿度影响使得PVDC适合蒸煮应用。在中国,PVDC广泛用于蒸煮应用中作为单层胶片;并兴趣在多层膜中掺入蒸馏器的多层膜的兴趣正在生长。

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