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PVDC Barrier Concepts for Demanding Coextrusion and Lamination Applications

机译:要求共挤出和层压应用的PVDC隔离层概念

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Copolymers of polyvinylidene chloride (PVDC), are-well known for their use in demanding barrier packaging applications to minimize the permeation of oxygen, water vapor, and odors. New die designs incorporating patented early encapsulation technology (US Patent 6,685,872, International Publication Number WO 02/06047, US Patent 4,643,927), coupled with temperature isolation technology developed by equipment suppliers, have eliminated degradation problems existing in the typical spiral mandrel dies used in the blown film process. These new die designs, coupled with new resin offerings; enable PVDC resins to be processed on large multilayer blown film dies. Multilayer films incorporating PVDC resins with higher temperature polymers such as Nylon, PP, and LLDPE in the skins are now possible. The advantage of coextruded multilayer films incorporating PVDC are that they offer, in a one step process, a combination of outstanding barrier performance, resistance to in-use conditions such as humidity and flex cracking, and specific physical properties given by the skin polymers. They represent the possibility of increasing product shelf life or down gauging the barrier material as well as reducing processing steps compared to laminated composite products. Its barrier performance being unaffected by humidity makes PVDC well suited for retort applications. In China, PVDC is widely used in retort applications as a monolayer film; and interest in incorporating PVDC in multilayer films for retort is growing.
机译:众所周知,聚偏二氯乙烯(PVDC)的共聚物可用于要求苛刻的阻隔包装应用中,以最大程度地减少氧气,水蒸气和气味的渗透。结合获得专利的早期封装技术(美国专利6,685,872,国际公开号WO 02/06047,美国专利4,643,927)的新模具设计,再加上设备供应商开发的温度隔离技术,消除了在模具中使用的典型螺旋心轴模具中存在的退化问题。吹膜过程。这些新的模具设计,以及新的树脂产品;使PVDC树脂可以在大型多层吹膜模具上加工。现在可以在皮肤中掺入PVDC树脂和耐高温聚合物(例如尼龙,PP和LLDPE)的多层薄膜。包含PVDC的共挤出多层薄膜的优势在于,它们可以在一个步骤的过程中提供出色的阻隔性能,对使用条件(例如湿度和弯曲龟裂)的抵抗力以及皮肤聚合物赋予的特定物理性能的组合。与层压复合产品相比,它们代表了增加产品保质期或降低阻隔材料厚度以及减少加工步骤的可能性。它的阻隔性能不受湿度的影响,使得PVDC非常适合于干馏应用。在中国,PVDC作为单层膜被广泛用于蒸煮应用中。对将PVDC掺入用于蒸煮的多层薄膜中的兴趣正在增长。

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