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Synthesis of graphene nanoribbons from amyloid fibrils by solid-phase graphitization using liquid gallium catalyst

机译:采用液相镓催化剂通过固相石墨化合成石墨烯纳米纤维纤维

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Amyloid fibrils, which are linear proteins with widths of less than 10 nm and lengths of more than 1 μm, were used as an amorphous carbon template for graphene nanoribbons (GNRs) synthesized by solid-phase graphitization using liquid Ga as the catalyst. The crystal quality of the GNRs improved with increasing synthesis temperature. However, the shape of the GNRs synthesized at temperatures higher than 900 °C became broader, losing the original amyloid shape, whereas the GNRs synthesized at 900 °C seemed to maintain the original amyloid shape in the SEM observation. The conducting paths of GNRs synthesized at 900 °C were found to be slightly diffused outside the topography of the GNRs in the conductive atomic force microscopy map. In addition, some of the sapphire terrace edges of the substrate showed conductivity, which indicates that the growth mechanism of graphene on a sapphire substrate might be a step-flow growth mode.
机译:淀粉样蛋白原纤维,其具有宽度小于10nm的线性蛋白,长度为1μm,用作通过使用液态Ga作为催化剂的固相石墨化合成的石墨烯纳米纤维(GNR)的无定形碳模板。随着合成温度的增加,GNR的晶体质量改善。然而,在高于900℃的温度下合成的GNR的形状变得更宽,失去了原始淀粉样蛋白形状,而在900℃合成的GNR似乎在SEM观察中保持原有的淀粉样蛋白形状。发现在900℃合成的GNR的导电路径在导电原子力显微镜图中的GNR的形貌外部略微扩散。另外,衬底的一些蓝宝石露台边缘显示导电性,这表明石墨烯对蓝宝石衬底的生长机制可能是阶梯流生长模式。

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