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NANO-SCALE RESIN MODIFICATIONS IN FIBERGLASS LAMINATES CONTAINING PLY DROPS

机译:含有层滴玻璃玻璃层压板的纳米级树脂修饰

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Fiberglass (Owens-Corning WindStrand) reinforced laminates containing internal ply drops were fabricated using resin film infusion with Epon 862 epoxy as the matrix resin. In addition, in the region of the ply drop, the resin was enhanced using two types of additive: DuPont Kevlar pulp and Applied Sciences Inc PR-25 vapor grown carbon nanofiber. Laminate lay-ups of [0/0*/0]_(T) and [+45/-45/0*/-45/+45]_(T) (where * indicates the ply that was discontinued) were tested in both static and fatigue loading. Failure typically initiated at the resin pocket formed at the termination of the dropped ply, which was detected by both edge photomicrographs and a jump in longitudinal strain at the ply drop location. For the [0/0*/0]_(T) laminates, addition of the Kevlar pulp resulted (when compared to the non-modified epoxy-only resin) in a large increase in the quasi-static stress required to initiate damage, and a slight increase in laminate strength. Addition of the carbon nanofiber resulted in essentially no change in the stress required to initiate damage, and a reduction in the ultimate strength. The trend for the [+45/-45/0*/-45/+45]_(T) laminates showed an appreciable increase in the damage initiation quasi-static stress in both the Kevlar pulp and PR-25 laminates, appreciably no change in ultimate strength due to the Kevlar pulp, and a notable ultimate strength increase due to the inclusion of the PR-25. Results from fatigue testing showed a large fatigue penalty (in the thin laminates) due to the inclusion of the ply-drop, and no statistically significant difference in fatigue life due to the inclusion of the nano-scale reinforcements. Finite element stress analysis modeling of the crack growth indicates the effects of having increased matrix modulus in the resin pocket zone, as well as increased value of laminate critical energy release rate. The analysis indicates the sequence of failure to be, first, the development of a transverse crack in the resin pocket, followed by delamination along the dropped ply. This sequence was confirmed by photomicrographs taken at fixed load intervals.
机译:使用具有EPON 862环氧树脂的树脂膜输注制造玻璃纤维(OWENS-康宁风声)含有内层滴的增强层压板作为基质树脂。另外,在帘布层的区域中,使用两种类型的添加剂来增强树脂:杜邦Kevlar纸浆和施加的SCIENCES Inc Pr-25蒸汽生长碳纳米纤维。 [0/0 * / 0] _(t)和[+ 45 / -45 / 0 * / - 45 / + 45] _(t)的层压粘附阶层(其中*表示已停止的帘布层)在静态和疲劳负载中。通常在在掉掉的层终止处形成的树脂袋处的失败,其通过边缘显微照片检测到帘布层下降位置处的纵向应变中的跳跃。对于[0/0 * / 0] _(t)层压材料,加入kevlar纸浆得到(与非改性的环氧树脂的树脂相比)大幅增加,以启动损坏所需的准静态应力,层压强度略有增加。添加碳纳米纤维导致引发损坏所需的应力基本上没有变化,以及降低最终强度。 [+ 45 / -45 / 0 * / - 45 / + 45] _(t)层压板的趋势显示,Kevlar纸浆和PR-25层压板中的损伤启动准静态应力显着增加,明显没有由于Kevlar纸浆引起的最终强度的变化,并且由于包含PR-25,具有显着的最终强度增加。由于含量下降,疲劳检测结果显示出大的疲劳罚球(在薄层压板中),并且由于包含纳米级增强而导致的疲劳寿命没有统计学显着差异。裂缝生长的有限元应力分析建模表明树脂袋区中具有增加的基质模量的影响,以及层压临界能量释放速率的增加值。分析表明,失败的序列首先,首先是树脂袋中的横向裂纹的发展,然后沿着掉落的层进行分层。通过以固定载荷间隔拍摄的显微照片来确认该序列。

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