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FUNCTIONALIZATION AND CHARACTERIZATION OF NANODIAMOND-DERIVED MULTI-LAYERED FULLERENES (CARBON NANO-ONIONS)

机译:纳米金刚胺衍生多层富勒烯(碳纳米离)的官能化与表征

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Carbon nano-onions (CNOs), discovered by Ugarte in 1992, are multi-layered fullerenes that are spherical analogs of multi-walled carbon nanotubes with a broad range of diameters. CNOs synthesized by graphitization of nanodiamonds (N-CNOs) with diameters from 6 to 10 nm and 7-10 graphitic layers are the subjects of our research. During graphitization of nanodiamonds, the preferential exfoliation of (111) and (110) planes takes place to form (001) graphitic planes. Typical N-CNOs with varying numbers of graphitic layers and their corresponding surface area and number of carbon atoms are shown in Fig. 1. N-CNOs are more reactive than other CNOs due to their smaller size, high curvature and perhaps density of surface defects. We are exploring potential applications in electronics, biology and polymer composites.
机译:由Ugarte于1992年发现的碳纳米洋葱(CNO)是多层富勒烯,其是具有宽范围直径的多壁碳纳米管的球形类似物。通过从6至10nm和7-10个石墨层的直径为直径的纳米金刚胺(n-CNOS)的石墨化合成的CNO是我们研究的主题。在纳米金刚石的石墨中,发生(111)和(110)平面的优先剥离,以形成(001)石墨平面。具有不同数量的石墨层及其相应的表面积和碳原子数和碳原子数的典型N-CNO如图1所示。N-CNOS由于其较小尺寸,高曲率和表面缺陷的密度而比其他CNO更具反应性。我们正在探索电子,生物学和聚合物复合材料中的潜在应用。

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