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Pressure-induced phase transitions of graphite intercalation compounds with bromine and aluminiums chloride

机译:用溴和氯化铝的石墨嵌入化合物的压力诱导的相变

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The paper presents the results of the investigations of basal plane resistivity pa under the pressure for disordered anisotropic pyro lytic graphite (APG) (L~3-10~(-8)m, doo23.40-lCTsm) and based on intercalated compounds (GICs) with bromine and aluminiums chloride. The samples of APG were intercalated by standard one-temperatures technique to the second stage. The investigations of specimen's resistivity under the pressure were carried out in the high hydrostatic pressure cell in the temperature range from 77K to 293K and pressure up to 1.2GPa. It is shown from the experimental investigations that resistivity of APG specimens is decreased under the pressure (Fig. 1, curves 1 and 2) in contrast to GICs for that's resistivity is increased under the pressure (Fig. 1, curve 3).
机译:本文介绍了基底平面电阻率PA在紊乱的各向异性波形裂解石墨(APG)(L〜3-10〜(-8)M,DOO23.40-LCTSM)下的压力下的研究结果,并基于插层化合物( GICS)用溴和氯化铝。通过标准一温技术将APG的样品嵌入到第二阶段。试样在压力下的电阻率的调查在高静液压压力单元中在温度范围为77k至293k,压力高达1.2gPa。从实验研究中显示出APG样品的电阻率在压力下减小(图1,曲线1和2),与该电阻率的GIC相反(图1,图1,曲线3)。

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