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Liquid Metal-assisted Fracture of the T91 Martensitic Steel

机译:T91马氏体钢的液态金属辅助骨折

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Use of liquid lead-bismuth eutectic (LBE) as spallation target or as cooling fluid in accelerated-driven systems rises the question of the reliability of structural materials in terms of liquid metal embrittlement, corrosion and corrosion-fatigue. The paper analyses the risks of corrosion damage and of accelerated fatigue damage by liquid lead-bismuth eutectic (LBE) of the T91 steel and consists of three parts. Firstly, the corrosion of the T91 in LBE is studied at CEA paying attention on the oxygen concentration. This results in dissolution process when the oxygen concentration is low while a protective oxide film forms under high oxygen concentration. The second part is devoted to the experiments carried out at Lille University on the low cycle fatigue behaviour of the T91 steel. It is shown that the stress response to strain cycling is not influenced by LBE. However, the fatigue resistance is reduced by a factor at least of 2 when cycling at 300°C in LBE instead of air. Finally, the third part takes into account at once the effects of corrosion damage and the effects of fatigue damage. A pre-immersion of T91 fatigue specimens in a LBE bath is carried out at CEA. The immersion temperature was 600°C for about 600 h and the dissolved oxygen concentration less than 10~10 wt.%. The average relative loss of mass estimated from reference plates was less than 0.3% as a result of dissolution process. The specimens are then fatigued at Lille University in the as-received conditions (no modification of the specimen surface before fatigue testing). Fatigue tests are carried out with the same experimental procedure in LBE at 300°C. The results obtained on the pre-corroded specimens show that the fatigue life is reduced by a factor of about 10. The role of LBE is then discussed on the bases of SEM metallographic observations. LBE appears to be not only a source of microcracks in T91 when dissolution process occurs but promotes as well the growth of short cracks nucleated by cyclic plasticity or of the sharp defects induced by corrosion. Finally, an oxide layer formed in oxygen saturated LBE behaves like a protective coating against fatigue damage in LBE. The present methodology and the obtained results are therefore of interest for innovative nuclear systems, such as Generation IV reactors, critical and subcritical transmutation systems and fusion devices.
机译:在加速驱动系统中使用液体铅 - 铋共晶(LBE)作为剥落靶或冷却流体在液态金属脆化,腐蚀和腐蚀 - 疲劳方面上升了结构材料可靠性问题。本文分析了T91钢的液体铅 - 铋铋(LBE)的腐蚀损伤和加速疲劳损伤的风险,包括三个部分。首先,在CEA中研究了LBE中T91的腐蚀,请注意氧气浓度。当氧浓度低而在高氧浓度下形成保护氧化物膜时,这导致溶解过程。第二部分致力于在利尔大学对T91钢的低循环疲劳行为进行的实验。结果表明,对应变循环的应力响应不受LBE的影响。然而,当在300℃以LBE而不是空气中循环时,疲劳电阻减少了至少2的因子。最后,第三部分立即考虑了腐蚀损伤的影响和疲劳损伤的影响。在CEA中进行LBE浴中T91疲劳试样的预浸渍。浸渍温度为600℃,约600小时,溶解的氧浓度小于10〜10重量%。由于溶解过程,由参考板估计的质量的平均相对损失小于0.3%。然后,在Lille University造成沉降的条件(在疲劳试验前没有修饰样品表面的修饰)疲劳。疲劳试验在300℃下以LBE的相同的实验程序进行。在预腐蚀试样上获得的结果表明,疲劳寿命减少了约10.然后在SEM金相观察的基础上讨论LBE的作用。当溶出过程发生时,LBE似乎不仅是T91中的微裂纹源,但随着循环可塑性或通过腐蚀引起的尖锐缺陷而升高的短裂缝的生长。最后,在氧气饱和LBE中形成的氧化物层的表现在LBE中的抗疲劳损伤的保护涂层类似。因此,本方法和所获得的结果对于创新的核系统,例如生成IV反应堆,临界和亚临界嬗变系统和融合装置的感兴趣。

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