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Study on properties of low-Ag content Sn-Ag-Zn lead-free solders

机译:低AG含量SN-AG-ZN无铅焊料的性能研究

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Sn-Ag solder has been regarded as the most promising solder which can in place of Sn-Pb solder in the future, but there are reliability and cost problems limit its use. Therefore low-Ag content Sn-Ag-Cu solder, SAC105 was researched, it also has some problems. On the other hand, Sn-Ag-Zn solder has some advantages comparing with Sn-Ag-Cu solder, but the low-Ag Content Sn-Ag-Zn solder isn't reported yet. In this paper, melt and tensile properties of Sn-xAg-1Zn (x=1, 2, 3) solders is researched, it was found the properties of Sn- 2Ag-1Zn solder much better than Sn-1Ag-1Zn solder. So we further researched the melt and tensile properties, solder joint strength on C194 substrate and microstructure of Sn-2Ag-xZn (x=1, 2, 3, 4) solders, otherwise, these solders with 0.1wt% Cr doping were also researched. The results show that when the Zn contains more than 3wt%, the liquidus would be decreased while the pasty range would be enlarged. Doping of Cr will increase the liquidus slightly, has little effect in general. In the tensile test, Sn-2Ag-2Zn solder has the best strength but the worst plasticity. Increasing Zn content will improve the plasticity while decrease the tensile strength. Doping of Cr will enhance tensile strength of the all solders and improve plasticity while the Zn content higher than 2wt%. In solder joint strength test, the as-soldered samples have similar strength. After a few days aging, the solders with high Zn content and doped with Cr have better strength. After 16 days aging, except Sn-2Ag-3Zn-0.1Cr solder, the strength of most solder joints is decreasing.
机译:Sn-Ag焊料一直被视为最有前途的焊接它可以在发生在未来的Sn-Pb焊料,但也有可靠性和成本问题限制了它的使用。因此低银含量的Sn-Ag-Cu系软钎料,SAC105进行了研究,它也有一些问题。在另一方面,锡 - 银 - 锌钎料有一定的优势的Sn-Ag-Cu系焊料相比,但低银含量锡 - 银 - 锌焊料国内尚未见报道。在本文中,熔融和Sn-XAG-1Zn的拉伸性能(X = 1,2,3)的焊料进行了研究,发现的Sn-2AG-1Zn的性质除Sn-1AG-1Zn焊料焊料好得多。因此,我们进一步研究的Sn-2AG-xZn的C194基板和微观结构上的熔体性能和拉伸性能,焊料的接合强度(X = 1,2,3,4)焊料,否则,这些焊料与0.1重量%的Cr掺杂也研究。结果表明,当锌包含比3重量%多,则液相将被同时糊状范围将扩大降低。掺杂铬会增加液相略,在一般影响不大。在拉伸试验中,Sn系2AG-2ZN焊料具有最佳的强度,但最坏的可塑性。增加Zn含量将提高可塑性而降低拉伸强度。的Cr的掺杂将增强所有焊料的抗张强度和改善可塑性大于2重量%,而Zn含量较高。在焊料接合强度试验中,作为钎焊的样品具有相似的强度。几天老化后,具有高锌含量和掺杂有铬焊料具有更好的强度。后16天老化,不同之处的Sn-2AG-性的3Zn-0.1Cr焊料,最焊点的强度下降。

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