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Behaviour of Various Glass Seal for Planar Solid Oxide Fuel Cell

机译:平面固体氧化物燃料电池的各种玻璃密封的行为

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摘要

One of the critical issues in designing a planar solid oxide fuel cell (SOFC) is the development of materials to hermetically seal the metal (430 series stainless steel) or ceramic interconnector with the ceramic electrolyte of the cell. The main objective of this sealing material is to achieve a low leak rate, long-term stability at operating temperature and chemical compatibility with other components. One of the compositions has been operated in an SOFC in excess of 30 minutes over the range of 600, 700, 800, and 900°C. The seal is a composition of polymer blend and glass of 1:3, 1:1 and 3:1 by weight. The leakage rate of each seal was measured simultaneously under the compressive force of 100 N, 2 bar Helium. The seal was characterized using a thermogravimetric analysis. The effect of glass composition on operating temperature and compressive forces on the leakage rate have been discussed and correlated.
机译:设计平面固体氧化物燃料电池(SOFC)的关键问题之一是在密封金属(430系列不锈钢)或陶瓷互连器与细胞的陶瓷电解质的发展中的开发。这种密封材料的主要目的是在操作温度和与其他组分的化学相容性下实现低泄漏率,长期稳定性。其中一种组合物在300,700,800和900℃的300,700,800和900℃的SOFC中以超过30分钟的30分钟操作。密封是聚合物共混物和玻璃的组成,1:3,1:1和3:1重量。在100n,2巴氦的压缩力下同时测量每个密封件的泄漏速率。密封的特征在于使用热重分析。讨论并相关讨论了玻璃组合物对渗漏速率的操作温度和压缩力的影响。

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