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Transient Infrared Spectroscopic Measurements of Reactive Materials using an Echelle Spectrometer

机译:梯度光谱仪的瞬态红外光谱测量反应材料

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When analyzing combustion events of energetic materials it is important to be able to determine reaction paths and local temperatures occurring during the reaction. Thus far, energetic diagnostics have primarily focused on collecting data in the visible region of the spectrum using optical spectroscopy techniques. The infrared region of the spectrum provides significant advantages because many important combustion intermediates have strong ground state vibrational transitions in the infrared that cannot be seen in the visible. Currently, the primary method of infrared spectroscopic measurements is through the use of Fourier transform infrared spectroscopy (FTIR). This method is restricted in temporal resolution which limits the method's utility in highly transient energetic applications. In this paper, an infrared echelle spectrometer is presented that is well suited for spectroscopic measurements of energetic materials. The spectrograph is used in conjunction with a Sofradir HgCdTe infrared image sensor and can be used for emission and absorption spectroscopic measurements in the 1-5 micron wavelength range. The echelle design permits a large spectral range (~2 μm) that cannot be achieved using rapid-scan Fourier transform infrared spectroscopy while maintaining a relatively high resolution of approximately 1 nm over the entire spectral range. The spectrometer was validated using the infrared absorption spectra of a known species in a gas cell.
机译:当分析能量材料的燃烧事件时,能够确定在反应过程中发生的反应路径和局部温度是重要的。到目前为止,精力充沛的诊断主要专注于使用光谱谱技术收集光谱的可见区域中的数据。光谱的红外区域提供了显着的优点,因为许多重要的燃烧中间体在红外线中具有强大的地位振动过渡,不能在可见中看到。目前,红外光谱测量的主要方法是通过使用傅里叶变换红外光谱(FTIR)。该方法受到时间分辨率的限制,其限制了该方法在高瞬态的能量应用中的实用程序。在本文中,提出了一种红外梯度光谱仪,其非常适合于能量材料的光谱测量。光谱仪与SOFRADIR HGCDTE红外图像传感器结合使用,可用于1-5微米波长范围内的发射和吸收光谱测量。梯孔设计允许使用快速扫描傅里叶变换红外光谱,不能实现的大的光谱范围(〜2μm),同时在整个光谱范围内保持约1nm的相对高分辨率。使用在气池中的已知物质的红外吸收光谱验证光谱仪。

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