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Rheology of Heavy Oil Emulsions

机译:重油乳液的流变学

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摘要

Water is invariably produced with crude oil. If there is enough shear force when crude oil and produced water flow through the production path, stable emulsions may be formed. This scenario may particularly be present during the production of heavy oils where steam is used to reduce the viscosity of heavy oil or in cases where submersible pumps are used to artificially lift the produced fluids. To efficiently design and operate heavy oil production systems, knowledge of the realistic viscosities of the emulsified heavy oil under the actual production conditions is necessary. This study is an attempt to investigate the effect of water content, pressure and temperature I.e. operating conditions on the viscosity of live heavy oil emulsions. Two heavy oil samples from South America were used for this study. The stock tank oil (STO) samples were recombined with the corresponding flash gases to reconstitute the original reservoir oil compositions. Live oil-water emulsions were prepared in a concentric cylinder shear cell using synthetic formation water, under predetermined pressure, temperature, and shear conditions. The stability of live emulsions was investigated using a fully visual PVT cell, while viscosities were measured using a pre-calibrated high-pressure capillary viscometer. Viscosities were measured at least in three different flow rates at the testing conditions. In addition to live oil emulsion studies, the stability and droplet size distribution of STO emulsions were also determined. Experimental results indicated that the inversion point for the stock tank oil emulsions was approximately 60 % water cut (volume) and that the average droplet size was increasing with water content. For all measured cases, viscosities varied with temperature according to an Arrhenius relation while viscosities did not indicate any variation with flow rate (shear) within the range of tested flow rates. Measured viscosities also increased as pressure decreased below the bubble point of the sample as lighter hydrocarbon components evolved. The measured viscosities increased as much as 500% due to the presence of emulsions before sharp drop in viscosity beyond the inversion point. The variation of viscosity with water content for live emulsion samples indicated that the inversion point for live emulsions is similar to that of stock tank oil samples.
机译:水总是用原油生产的。如果原油并产生通过生产路径的水流时有足够的剪力力,则可以形成稳定的乳液。在生产重油中的生产过程中可能特别存在这种情况,其中蒸汽用于降低重油的粘度或在潜水泵用于人工提升所产生的流体的情况下。为了有效地设计和运营重油生产系统,需要了解实际生产条件下乳化重油的现实粘度。该研究表明探讨了水含量,压力和温度的影响。活性重油乳液粘度的操作条件。来自南美洲的两种重油样品用于本研究。用相应的闪光气体重新组合储物油(STO)样品,以重建原始储层油组合物。使用合成形成水在预定的压力,温度和剪切条件下在同心圆柱剪切电池中制备活油乳液。使用完全视觉PVT细胞研究了活乳液的稳定性,而使用预校准的高压毛细管粘度计测量粘度。在测试条件下至少以三种不同的流速测量粘度。除了活油乳液研究外,还测定了STO乳液的稳定性和液滴尺寸分布。实验结果表明,储物油乳液的反演点约为60%的水切(体积),平均液滴尺寸随水含量增加。对于所有测量情况,根据Arrhenius关系的温度随温度而变化的粘度,而粘度没有指示在经过测试的流速范围内的流速(剪切)的任何变化。测量粘度也随着样品的气泡点降低而增加,作为较轻的烃组分进化。由于乳液在粘度急剧下降超过倒置点之前,测量的粘度增加了多达500%。用于活乳液样品的水含量的粘度的变化表明,活乳液的反演点类似于储备油样品。

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