Hydrothermal synthesis and structure determination of UH-6 and UH-8:Two novel zincophosphates containing cobalt complexes

摘要

The aim of structure-directed synthesis is the designed preparation of novel solid-state structures by using the structure-directing functions of some molecular additive,the so-called structure-directing agent (SDA).Work in our group has shown that cobalt complexes with amine ligands exert strong structure-directing effects in the synthesis of zincophosphates.Here we report the structures of the novel zincophosphates UH-6 and UH-8 which have been synthesized using the cage-like cobalt complexes [CodiAMsar]~(3+) and [Cosep]~(3+),respectively,as SDA.