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Thermodynamics Investigations for the Adsorption of Carbon Dioxide on Different Rocks

机译:热力学研究对不同岩石上二氧化碳吸附的研究

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This papers deals with climate change and geological sequestration. The adsorption of carbon dioxide investigation into clay minerals such as e.g. montmorillonite and kaolinite is investigated. There are three types of interactions between carbon dioxide and the bulk of geological formations. Carbon dioxide can be either trapped as a gas or supercritical fluid (so called hydrodynamic trapping), or dissolved into the groundwater (so called solubility trapping), or adsorbed on the surface of rocks or it may -after a longer period- react with minerals in the geological formations leading into the precipitation of carbonate minerals (so called mineral trapping). This sequestration process is based on carbon dioxide adsorption or absorption into the clay minerals. In our experiments, dry and wet minerals were exposed to carbon dioxide environment at temperatures 25°C and 40°C under pressure in the range of 0,01 to 150 bar. Further, the measurements of grain size dependency on the carbon dioxide ad/absorption is also presented. All investigations were carried out with high precision in a magnetic suspension balance (Rubotherm, Germany). Experiments show a surprising high loading of the minerals by CO_2. Further, there are remarkable differences between the individual minerals.
机译:本文涉及气候变化和地质封存。将二氧化碳调查吸附成粘土矿物,例如例如,如例如。蒙脱石和高岭石进行了调查。二氧化碳与大部分地质形成之间存在三种类型的相互作用。二氧化碳可以被捕获为气体或超临界流体(所谓的流体动力捕获),或溶解到地下水(所谓的溶解度俘获)中,或吸附在岩石表面上,或者它可以更长的时间 - 与矿物反应在地质形成中导致碳酸盐矿物沉淀(所谓的矿物捕获)。该螯合过程基于二氧化碳吸附或吸收到粘土矿物中。在我们的实验中,干燥和湿矿物在25℃和40℃的温度下暴露于二氧化碳环境,在0.01至150巴的压力下。此外,还提出了对二氧化碳AD /吸收的晶粒尺寸依赖性的测量。所有调查都以高精度的磁悬浮余额(Rubotherm,Germany)进行。实验表明CO_2令人惊讶的高负荷矿物质。此外,各个矿物质之间存在显着的差异。

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