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Thermo-Kinetic Model of Pyrolysis

机译:热解的热动力学模型

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A substantial number of studies have been dedicated to development of mathematical models that describe degradation of solid materials exposed to external heat flux. These models range in their complexity from analytical formulations based on assumption of a steady-state to complete, numerical solutions of the transient heat and mass transport coupled with chemical reactions. Most of these models are one-dimensional. They predict the rate of mass loss from a unit area of the exposed surface. Some models incorporate a description of the gas-phase combustion. Such models are frequently used to simulate the spread of flame (flame spread models are usually two-dimensional). Potentially, these models can be employed to understand and predict materials flammability. However, their utilization has been hampered by reliance on assumptions that make each of them applicable to a relatively narrow range of conditions and limited number of materials.
机译:大量研究致力于开发数学模型,描述暴露于外部热通量的固体材料的降解。这些型号的复杂性从分析配方基于稳态的假设完成,瞬态热量和大规模转运与化学反应的稳态溶液的数值溶液。这些模型中的大多数是一维的。它们预测来自暴露表面的单位面积的质量损失率。有些型号包含气相燃烧的描述。这些模型经常用于模拟火焰的扩散(火焰扩展模型通常是二维的)。可能,这些模型可以用于理解和预测材料易燃性。然而,依赖于使每个适用于相对狭窄的条件范围和有限的材料的假设,它们的利用被阻碍了。

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