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Hierarchical Self-Assembly of Hydrogen- Bonded Block Copolymer Complexes in Organic Solvents

机译:有机溶剂中氢键嵌段共聚物复合物的分层自组装

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The micellization of diblock copolymers in a selective solvent for one of the blocks is a very useful method to produce well-defined nano-objects that may be useful for a variety of applications. Micelles from diblock copolymers are characterized by a rather simple structure consisting of a core formed by the insoluble blocks surrounded by a corona of the soluble blocks. Although spherical micelles are the most widely reported examples, other morphologies including rods, vesicles and other intricate morphologies have been described, depending on the chemical nature and of the composition of the diblock copolymers. Moreover, more complex structures than core-corona micelles have been obtained whenever ABC triblock copolymers are considered for micellization. In that respect, various multicompartment micelles have been recently obtained. Information on these micelles can be found in a recent review.
机译:二嵌段共聚物在选择性溶剂中的二嵌段共聚物的胶束化是制备可用于各种应用的良好定义的纳米物体的非常有用的方法。来自二嵌段共聚物的胶束特征在于由由由可溶性块的电晕笼围绕的不溶性块形成的芯组成的相当简单的结构。尽管球形胶束是最广泛报道的实例,但已经描述了包括棒,囊泡和其他复杂形态的其他形态,这取决于二嵌段共聚物的组成。此外,只要考虑ABC三嵌段共聚物,已经获得了比核心 - 电晕胶束的结构更复杂的结构。在这方面,最近已经获得了各种多组分胶束。有关这些胶束的信息可以在最近的审查中找到。

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