Electron transfer in reaction centers within two-dimensional model.New role of local charges

摘要

Electron transfer (ET) reactions in reaction centers (RC) are considered within a two-dimensional model.The key points of the model are the separate contributions of temperature independent vibrationa] (v) and temperature dependent diffusive (d) coordinates to the preexponential factor,to the reorganization energy lambda=lambda_v+lambda_d(T) and to the free energy of reaction DELTA G = AG_v+ DELTA G_d(T).