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Electrochemically induced diastereoselective functionalization of N-acyloxazolidin-2-ones

机译:电化学诱导的N-酰胺唑烷蛋白-2-酮的官能化官能化

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摘要

Chiral N-acyloxazolidin-2-ones are valuable intermediates and building blocks in asymmetric organic synthesis.In fact,they can be used for efficient diastereoselective C-C bond constructions in chiral enolate-derived reactions (such as alkylations,acylations,etc.) wherein the chiral auxiliary is both readily obtained and easily recovered after the desired bond construction has been achieved.
机译:手性N-酰氧唑嗪-2-唑类 - 2-含有有价值的中间体和非对称有机合成的构建块。事实上,它们可用于手性烯醇烯醇酯的反应(例如烷基,酰化等)中的有效的非对映选择性CC键合结构。在实现所需的粘合结构之后,手性助剂均易于获得并且容易恢复。

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