Preparation of Organofluorine Compounds by the Anodic Oxidative Fluorination of Iodine Compounds

摘要

Preparation of organo-fluorine compounds has been successfully performed through the anodic oxidation of iodine compounds in the presence HF-Base electrolyte, namely, elctrochemical chemoselective fluoro-deiodination of alkyl iodides to prepare the corresponding alkyl fluorides (eq. 1) and elctrochemical iodo-fluorination of alkenes using tetra-alkyl ammonium iodides (eq. 2).