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Preparation and characterization of nanometer-scale polycarbonate fibers:bead formation

机译:纳米级聚碳酸酯纤维的制备与表征:珠粒形成

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Electrospinning is a superior process compared to other conventional spinning methods for the production of fibers in the sub-micron to nanometer scale.Such fiber membranes have exceptionally large surface areas and small pore sizes.The process requires an electrostatic force,which induces chages on the liquid droplet of the polymer solution or melts and therefore overcomes the jet dries or solidifies,an electrically charged fiber remains,which can be directed or accelerated by the electrical forces and then collected in non-woven fiber membrane or other useful shapes.The present research work demonstrates the electrospinning of polycarbonate solution with solvent mixtures THF (Tetrahydrofuran) and DMF (Di-methyl formamide) to produce nanometer scale polycarbonate fibers.The solvent mixture of THF and DMF was the major nanometer scale polycarbonate fibers.The solvent mixture of THF and DMF was the major parameter for producing nano-polycarbonate fibers along with the formation of byproducts beads.The electrostatic voltage,viscosity and surface tension also showed significant effecton bead formation and bead density.The microstructures of the polycarbonate beads were quantively investigated by Scanning Electron Microscopy (SEM) and Transmission Electron Microscope (TEM).
机译:与其他常规纺丝方法相比,静电纺丝与亚微米中的纤维的其他常规纺丝方法相比。纤维膜具有异常大的表面积和小的孔径。该过程需要静电力,从而诱导凹槽聚合物溶液或熔体的液滴,因此克服喷射干燥或凝固,留下电荷的纤维,其可以通过电力引导或加速,然后在非织造纤维膜或其他有用的形状中收集。目前的研究工作证明了用溶剂混合物THF(四氢呋喃)和DMF(二甲基甲酰胺)的聚碳酸酯溶液的静电纺丝,以产生纳米级聚碳酸酯纤维。THF和DMF的溶剂混合物是主要的纳米级聚碳酸酯纤维。THF的溶剂混合物和DMF是生产纳米聚碳酸酯纤维以及形成BYPRO的主要参数管道珠子。静电电压,粘度和表面张力也显示出显着的珠子形成和珠粒密度。通过扫描电子显微镜(SEM)和透射电子显微镜(TEM)定时研究了聚碳酸酯珠粒​​的微观结构。

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