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Preparation and characterization of polycarbonate/multiwalled carbon nanotube nanocomposites

机译:聚碳酸酯/多壁碳纳米管纳米复合材料的制备与表征

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摘要

A polymer nanocomposite was produced by ultrasonic-assisted dispersion of multiwalled carbon nanotubes (MWCNTs) in a polycarbonate matrix using p-xylene and dichloromethane as the solvents. The filler loading was varied from 1 to 3 wt % in order to examine the effect of MWCNTs on the structure and properties of the composites. The nanocomposites were characterized by DSC, DTA, TGA, UV–vis, FTIR and Raman spectroscopy to evaluate the changes induced by the filler in the polymer matrix. UV–vis, FTIR and Raman spectroscopy measurements confirmed the presence of the dispersed phase in the composite films, while TGA and DSC analysis of the nanocomposites revealed enhanced thermal stability and decreased crystallinity, respectively, as compared to the neat polymer. The proposed composites can find application in a number of everyday products where polycarbonate is the base polymer.
机译:使用对二甲苯和二氯甲烷作为溶剂,通过将多壁碳纳米管(MWCNT)超声辅助分散在聚碳酸酯基质中来生产聚合物纳米复合材料。为了检查MWCNT对复合材料的结构和性能的影响,填料的负载量在1至3wt%之间变化。通过DSC,DTA,TGA,UV-vis,FTIR和拉曼光谱对纳米复合材料进行表征,以评估聚合物基质中填料引起的变化。紫外可见,FTIR和拉曼光谱测量证实了复合膜中存在分散相,而与纯聚合物相比,纳米复合材料的TGA和DSC分析分别显示出增强的热稳定性和降低的结晶度。所提出的复合材料可用于以聚碳酸酯为基础聚合物的许多日常产品中。

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