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Influence of Different Accelerators on the Rheology and Early Hydration of Cement Paste

机译:不同加速器对水泥浆液流变和早期水合的影响

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摘要

Special applications like pumping, spraying or printing of concrete require the precise adjustment of very specific rheological properties at different time steps during the casting process. Superplasticizers such as polycarboxylate ethers (PCE) can be used to obtain the required flowability, which, possibly in combination with additional rheology modifying admixtures, generate the required specified consistency. However, after the application, the concrete should change the rheological properties immediately in order to avoid deformations at rest. Therefore, the use of accelerators can be effective. Accelerators influence the hydration of cementitious materials, and thus the rheological properties over the course of time and the setting. In this paper, the influence of different accelerators on the rheology and early hydration of cement paste as well as the interaction of accelerator and PCE are presented. Methods like rheometry, needle penetration tests and practical tests like spread flow were applied. The used accelerators showed accelerating behavior on the cement pastes without and in the presence of PCE. At the same time an influence on the rheology could be observed. This effect was less in the mixes with PCE, especially at the highest water/cement ratio (w/c).
机译:像泵送,喷涂或混凝土印刷等特殊应用需要在铸造过程中在不同时间步骤中精确调整非常特异的流变性质。诸如多羧酸醚醚(PCE)的超塑性剂可用于获得所需的流动性,可能与其他流变学改性混合物组合,产生所需的指定一致性。然而,在申请之后,混凝土应立即改变流变性能,以避免静止的变形。因此,使用加速器可以有效。加速器影响水泥材料的水合,从而影响随着时间的推移和环境的流变性质。本文介绍了不同促进剂对水泥浆液流变和早期水合的影响及加速器和PCE的相互作用。施加了流变性,针渗透试验和实际测试等方法。使用的加速器在没有和PCE存在下,在水泥糊中显示出加速行为。同时可以观察到对流变学的影响。在具有PCE的混合物中,这种效果较少,尤其是最高水/水泥比(W / C)。

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