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Thermodynamic properties of interstitial alloy FeC with BCC structure under pressure

机译:压力下具有BCC结构的间质合金FEC的热力学性质

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The analytic expressions for the thermodynamic quantities such as the mean nearest neighbor distance,the free energy,the isothermal compressibility,the thermal expansion coefficient,the heat capacities at constant volume and at constant pressure of binary interstitial alloy with body-centered cubic(BCC)structure and the small concentration are derived by the statistical moment method.The theoretical results are applied to the interstitial FeC alloy in the interval of temperature from 50 to 1000K and in the interval of interstitial atom concentration from 0 to 5%.In special cases,we obtain the thermodynamic quantities of the main Fe metal.Our calculated results for the thermal expansion coefficient and the heat capacity under constant pressure of main metal Fe are in good agreement with experiments.
机译:用于热力学量的分析表达式,如平均最接近邻距离,自由能,等温可压缩性,热膨胀系数,恒定体积处的热容,与身体为中心的立方(BCC)的二元间质合金的恒定压力结构和小浓度由统计矩法得出。理论结果以50至1000k的温度间隔和间隙间隔施加到间隙FEC合金,并且在间质原子浓度为0%至5%。在特殊情况下,我们获得了主要Fe金属的热力学批量。我们计算的热膨胀系数的结果和主金属Fe恒定压力下的热容量与实验吻合良好。

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