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Selective Recovery of Copper from Nickel Laterite Leach Solution

机译:从镍红土浸出溶液中选择性恢复铜

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The hydrometallurgical extraction of metals from nickel laterite ores has been developed in order to make the process technically and economically feasible. The treatment of leach solutions by different separation techniques have been studied. The primary metal to be recovered from laterite ore is nickel. Other metals of economic interest include cobalt and copper. Copper is very important for the automotive industry and, especially, electronics. Treatment of leach solutions by oxidation and hydroxide precipitation have the main problem of the co-precipitation of other metals. The iron precipitation process from nickel laterite leach solutions leads to metal losses by co-precipitation of copper and cobalt. The aim of this work was to study a selective precipitation of copper through the reduction process. Sodium dithionite was used as a reducing agent. The effect of precipitation time was studied; varying between of 30-120 min. Results showed that 77 % of the precipitate is composed of copper sulfide while, the remaining sulfur arising from the sulfate in the solution and the decomposition of the reducing agent. Analysis of the solution shows that 97 % of the copper precipitates and confirms the possibility of selective copper recovery.
机译:已经开发出来自镍红土矿石的金属的液压冶金提取,以便在技术上和经济上可行的过程。研究了通过不同的分离技术进行浸出溶液。从红土矿石中回收的初级金属是镍。其他经济利益金属包括钴和铜。铜对汽车行业非常重要,特别是电子。通过氧化和氢氧化物沉淀处理浸出溶液的主要问题是其他金属的共沉淀。来自镍红土浸出溶液的铁沉淀方法通过共析铜和钴而导致金属损失。这项工作的目的是通过减少过程研究铜的选择性降水。二硫代钛矿用作还原剂。研究了沉淀时间的效果;在30-120分钟之间变化。结果表明,77%的沉淀物由硫化铜组成,而溶液中产生的剩余硫和还原剂的分解。溶液分析表明,97%的铜沉淀并证实了选择性铜回收的可能性。

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