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Removal of hydrogen sulfide on activated carbon supported ionic liquids

机译:去除活性炭负载碳的离子液体上的硫化氢

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In this study, ionic liquid loaded activated carbon was applied as the adsorbent for hydrogen sulfide (H2S) removal under the anaerobic conditions in a fixed bed. The effects of activated carbon substrate, ionic liquid, initial H2S concentration and flow rate on the adsorption process were systematically studied. The experimental results show that the activated carbon named AC-1 having higher surface area and micropore volume is more suitable as the support for ionic liquid. Amongst three ionic liquids studied, the l-ethyl-3-methylimidazolium acetate loaded activated carbon exhibites the highest H2S sorption capacity performance. As a results of the superior performance of the l-ethyl-3-methylimidazolium acetate loaded activated carbon, further tests and characterizations were performed on the sorbent. The breakthrough capacity of l-ethyl-3-methylimidazolium acetate sorbent is two times greater than pure activated carbon. In addition, it is confirmed that increasing H2S concentration enhances H2S adsorption capacity, and the adsorption capacity of H2S decreases significantly with increasing gas flow rate.
机译:在该研究中,将离子液体液体负载活性炭作为在固定床中的厌氧条件下除去硫化氢(H2S)的吸附剂。系统地研究了活性炭基材,离子液体,初始H2S浓度和流速对吸附过程的影响。实验结果表明,具有较高表面积和微孔体积的AC-1的活性炭更适合作为离子液体的载体。在研究的三种离子液体中,L-乙基-3-甲基咪唑氨酸载负载活性炭展示了最高的H2S吸附能力性能。作为乙酸L-乙基-3-甲基咪唑鎓乙酸活性炭的优异性能的结果,对吸附剂进行了进一步的测试和表征。 L-乙基-3-甲基咪唑鎓乙酸盐吸附剂的突破容量比纯活性炭大的两倍。另外,证实增加的H 2 S浓度增强了H 2 S吸附能力,并且H 2 S的吸附容量随着气体流速的增加而显着降低。

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