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Protecting the food supply chain from farm to fork: Utilizing SERS and portable Raman spectroscopy

机译:保护食品供应链从农场到叉子:利用SERS和便携式拉曼光谱

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Ensuring food safety in various steps along the entire food value chain is crucial to prevent undesired and harmful substances entering the food humans consume. Pesticides and antifungal agents used during growth, processing or along the logistic chain from the field to the consumer can be toxic causing a range of symptoms from stomach pain to the death of the consumer even at trace levels of concentrations. To prevent dangerous additives and contaminants entering the food chain governmental restrictions on a large number of hazardous components have been put into place and are tightly monitored. For a large number of tests complex and sophisticated equipment is required along with time consuming sample preparation steps, not permitting instantaneous sampling of the specimen at the point of measurement or in a timely manner. In order to become a commercially applicable technique, the complexity of the sample preparation and the analysis routine needs to be simplified without losing performance in terms of identification and quantification of the dangerous contaminants. Raman spectroscopy is a technology to allow for quick and rigid analysis of materials without a large amount of sample preparation. The use of surface enhancement of the Raman signal by means of gold or silver nanoparticles would allow for taking this measurement to the field with high accuracy for even small concentrations. The high cost and poor reproducibility of commercially available substrates has so far limited the successful application of SERS measurements along the food value chain. The use of an affordable handheld Raman instrument with mass-producible SERS substrates will be described in the frame of the contribution with respect to requirements imposed at various stages along the food value chain.
机译:确保沿着整个食物价值链的各个步骤中的食品安全至关重要,以防止不期望和有害物质进入食物人类消费。在生长期间使用的杀虫剂和抗真菌剂,从现场到消费者的逻辑链中使用的物流链可能是毒性导致一系列症状,即使在痕量的浓度下也是消费者的死亡。为防止危险的添加剂和污染物进入食物链对大量危险部件的政府限制已经到达并严格监测。对于大量测试,需要复杂和复杂的设备,以及耗时的样品准备步骤,不允许在测量点或及时瞬时取样样品。为了成为一种商业上适用的技术,需要简化样品制剂的复杂性和分析程序的鉴定和定量危险污染物的定量而不失去性能。拉曼光谱是一种允许在没有大量样品制备的情况下快速且刚性的材料分析。通过金或银纳米粒子使用拉曼信号的表面增强将允许以高精度为甚至小浓度对该领域进行这种测量。商业上可获得的基材的高成本和再现性差,因此沿着食品价值链的成功应用Sers测量的成功应用。将在沿着食品价值链处于各个阶段施加的各个阶段的贡献的贡献框架中描述具有大量生产SERS基板的经济实惠的手持式拉曼仪器的使用。

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