(00609)Nitrogen co-doped with fluorine on reduced graphene oxide for enhanced electrocatalytic activity and stability for ORR in alkaline fuel cells

摘要

Nitrogen co-doped with fluorine on reduced graphene oxide (N-F-rGO)was prepared by one-pot hydrothermal treatment method. The scanning electron microscopy (SEM)images and X-ray photoelectron microscopy (XPS)spectra revealed the successful doping of nitrogen and fluorine into the rGO. The Brunauer-Emmett-Teller (BET)results demonstrated high surface area of N-F-rGO that are favorable for O2 adsorption. The results show that N-F-rGO catalyst has improved the catalytic performance electrode for the ORR in alkaline environment than the fluorine undoped N-rGO. The Koutechy-Levich (KL)analysis and rotating ring disk electrode (RRDE)measurements suggest that N-F-rGO dominantly favors a 4e- reduction process. The nitrogen co-doped with fluorine on rGO exhibited remarkable long-term stability towards the ORR than Pt/C. These improved electrochemical properties indicate that N-F-rGO will be promising candidates for cost-effective electrode materials for application of non-polluting alternative energy sources.