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Electrical Resistivity of Expanded Liquid Carbon at High Temperatures and High Pressures

机译:高温下膨胀液态碳电阻率和高压

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Specimens of high density graphite, anisotropic (2.2 g·cm~(-3)) and isotropic (2.0 g·cm~(-3)), were heated over several microseconds by an electrical pulse in thick-walled sapphire tubes. The transition of the liquid carbon's electrical resistivity from semimetal to metal-like characteristics was obtained at a high input energy (25-5 MJ·kg~(-1)). A comparison with similar effects for metals is discussed. Graphite's melting temperature of 4800 K is used for the high temperatures calculations. Temperatures higher than the melting point were roughly estimated, using previously measured Cv value (heat capacity under constant volume). The estimated temperature at the input energy (75 MJ·kg~(-1)) for liquid carbon (density 1.76 g·cm~(-3)) is ~23,000 K, with a correspondent measured electrical resistivity of 3,000 μΩ cm. The estimated temperature reached is ~35,000 K (electrical resistivity of ~1600 μΩ cm) for the liquid carbon (density 1.38 g·cm~(-3)) at the maximum input energy (110 MJ·kg~(-1)).
机译:高密度石墨,各向异性(2.2g·cm〜(-3))和各向同性(2.0g·cm〜(-3)),通过厚壁蓝宝石管中的电脉冲在几微秒内加热几微秒。在高输入能量(25-5MJ·kg〜(-1))下获得液体碳的电阻率从半型到金属样特性的电阻率。讨论了与金属类似效果的比较。石墨的熔融温度为4800 k用于高温计算。使用先前测量的CV值(在恒定体积下的热容量下)粗略地估计高于熔点的温度。用于液态碳的输入能量(75MJ·kg〜(-1))的估计温度(密度1.76g·cm〜(-3))是〜23,000 k,相应的电阻率为3,000μΩcm。达到的液态碳(密度1.38g·cm〜(-3))处于〜35,000k(电阻率为1600μΩcm),最大输入能量(110 mj·kg〜(-1))。

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