Reactions of Alpha Nucleophiles

机译：α亲核试剂的反应

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S_(N)2 and E2 are prototypical organic mechanisms: (1) Extensively studied in solution; (2) Less known about gas-phase analogs. Kinetic isotope effects (k_(H)/k_(D)): (1) Reveal competition between S_(N)2 and E2 reactions. Isotope labeling: (1) Reveals new reaction mechanisms. Alpha nucleophiles (XO~(-)): (1) Enhanced reactivity in solution; (2) Gas phase reactivity remains controversial.

机译：S_（n）2和E2是原型有机机制：（1）在溶液中广泛研究; （2）关于气相类似物的较少。动力学同位素效应（K_（h）/ k_（d））：（1）显示S_（n）2和E2反应之间的竞争。同位素标记：（1）显示出新的反应机制。 α亲核官（XO〜（ - ））：（1）溶液中的反应性增强; （2）气相反应性仍然存在争议。

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《American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics》|2009年||共1页
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Stephanie M. Villano; Nicole Eyet; W. Carl Lineberger; Veronica M. Bierbaum;
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3. Reactions of alpha-Phosphoryl-alpha-haloacetaldehydes with Difunctional Nucleophiles [J] . Kh.A.Asadov, R.N.Burangulova, E I.Guseinov Russian Journal of Organic Chemistry . 2005,第4期

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4. Reactions of Alpha Nucleophiles [C] . Stephanie M. Villano, Nicole Eyet, W. Carl Lineberger, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2009

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5. The reaction mechanism and alpha-effect in nucleophilic displacement at the phosphorus center of the pesticide, fenitrothion, by oxygen nucleophiles in aqueous medium. [D] . Omakor, Emegbero John. 1998

机译：在水性介质中，氧亲核试剂在杀虫剂磷中心杀nitro硫磷的亲核取代反应中的反应机理和α效应。
6. Unprecedented nucleophile-promoted 17-S or Se shift reactions under Pummerer reaction conditions of 4-alkenyl-3-sulfinylmethylpyrroles [O] . Takashi Go, Akane Morimatsu, Hiroaki Wasada, 2018

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7. Reactions of alpha-nucleophiles with a model phosphate diester [O] . Anthony J. Kirby, Alex M. Manfredi, Bruno S. de Souza, 2008

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8. Reaction of gem-Dichloroallyllithium with Aldehydes, Ketones, and Other Organic Substrates. An Example of Electronic Control of Regioselectivity in the Reactions of an Ambident Nucleophile. [R] . Seyferth, D., Murphy, G. J., Mauze, B. 1977

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Reactions of Alpha Nucleophiles

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