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Effect of Sodium Silicate Properties in Alkali-Activation of Mexican Blast Furnace Slag

机译:含硅酸钠特性在墨西哥高炉渣碱活化中的影响

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The present work is a study on alkali activation of Mexican blast furnace slag, using sodium silicate. The aim is to produce an optimal specimen, homogeneous without carbonation, and with small fraction of crystalline phases, similar to CSH, which provide mechanical properties suitable to use in the construction industry. The samples were prepared using sodium silicate activator solutions with modulus (SiO_2/Na_2O) of 1.25, 1.5, and 1.75. The weight percentage of Na_2O in the activator solutions was added at 4, 6 and 8% relative to the slag weight. The prepared samples were stored in sealed molds, at room temperature (20°C), during 7 days. The X-ray diffraction has revealed the presence of an amorphous phase, semi crystalline clinotobermorite phase and signals of calcium carbonate for the samples of 4 and 6% of Na_2O; in contrast with the 8% Na_2O, where the latter signals almost disappeared. The specimen selected as optimal was prepared with an activator concentration of 8% of Na_2O/Slag, and SiO_2/Na_2O of 1.25. A specimen under these optimal conditions was prepared with accelerated curing (40°C, humidity, 48 hours), and a compressive strength test was attained, with an average value of 52 MPa at 3 days.
机译:目前的作品是使用硅酸钠的墨西哥高炉炉渣的碱活化研究。目的是产生最佳的样品,无碳酸化均匀,并且具有较小的结晶相,类似于CSH,可提供适合于建筑业使用的机械性能。使用硅酸钠活化剂溶液制备样品,其模量(SiO_2 / Na_2O)为1.25,1.5和1.75。相对于炉渣重量,将活化剂溶液中Na_2O的重量百分比加入4,6和8%。在7天内,将制备的样品在室温(20℃)下储存在密封模具中。 X射线衍射揭示了非晶相,半结晶临床晶晶相和碳酸钙的信号,用于4和6%Na_2O的样品;与8%NA_2O相比,后一个信号几乎消失了。选择作为最佳选择的样本制备,其活化剂浓度为8%的Na_2O /渣,SiO_2 / Na_2O为1.25。通过加速固化(40℃,湿度,48小时)制备在这些最佳条件下的样品,并且在3天内实现压缩强度试验,平均值为52MPa。

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