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Characterization of the Stainless Steel Corrosion Kinetic By EIS

机译:EIS的不锈钢腐蚀动力学的表征

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An electrochemical study was carried out in order to obtain the effects of the turbulent flow condition on the stainless steel corrosion immersed in natural seawater using an electrochemical corrosion technique like electrochemical impedance spectroscopy (EIS). A three-electrode electrochemical glass cell was used to obtain the electrochemical measures, where a cylinder of the AISI 410 stainless steel was used as working electrode, a saturated calomel electrode as reference electrode and a synthesised graphite rod as auxiliary electrode. 24 hours was the total exposure time. In order to control the hydrodynamic conditions a rotating cylinder electrode (RCE) was used and, a scanning electron microscope (SEM) was used in order to obtain the superficial analyses of the metallic surface after tests. The results of the electrochemical techniques shown that at 1000 rpm of the rotation speed, the corrosion rate (CR) increased as the exposure time also increased. In additions, in the other rotations speed (2000, 3000 and 5000 rpm), the CR was affected by the corrosion products formed on metallic surface, t is important to point out that the corrosion morphology found in the steel sample was localized corrosion.
机译:进行了电化学研究,以便使用电化学阻抗光谱(EIS)等电化学腐蚀技术在天然海水中浸没在天然海水中的不锈钢腐蚀的影响。使用三电极电化学玻璃电池来获得电化学措施,其中AISI 410不锈钢的圆筒用作工作电极,饱和的Calomel电极作为参比电极和合成的石墨棒作为辅助电极。 24小时是完全暴露时间。为了控制流体动力学条件,使用旋转汽缸电极(RCE),并且使用扫描电子显微镜(SEM)以在测试后获得金属表面的浅表分析。电化学技术的结果表明,在1000rpm的转速时,随着曝光时间的增加也增加了腐蚀速率(Cr)。另外,在另一个转速(2000,3000和5000rpm)中,CR受金属表面上形成的腐蚀产物的影响,T是重要的,指出钢样品中发现的腐蚀形态是局部腐蚀的。

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