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POROUS SiC CERAMIC FROM WOOD CHARCOAL

机译:来自木炭的多孔SiC陶瓷

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摘要

Development of Bio-SiC materials with tailor made microstructure and properties using natural biopolymeric cellulose template are of great current interest. Porous (3-SiC ceramic has been fabricated by different methods using wood charcoal infiltrated with silica sol as well as single step method by using pine wood powder. Pine wood charcoal impregnated with resin and subsequent carbothermal reduction process at 1650°C in inert Ar atmosphere produced light weight biomorphic ?-SiC ceramic with good mechanical properties and porosities. The highly anisotropic cellulose structure of pine wood generates novel cellulose ceramics with a meso and macro porous structure pseudomorphous to the initial porous tissue skeleton. Microstructural observation and phase identification of resulting wood ceramics have been performed by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. Weight loss during heating of wood and phenolic resin in N_2 atmosphere was investigated by thermogravimetric analysis (TGA). Experimental results showed that porous ?-SiC possessed topologically homogenous pore structure. This provides a low- cost and ecofriendly route to advanced ceramic materials, with near-net shape potential.
机译:采用天然生物聚合物纤维素模板生物碳化硅材料与量身定制的组织和性能的发展是目前各方关注的。多孔(3-碳化硅陶瓷已通过使用木材不同的方法制造的活性炭渗入与硅溶胶以及通过使用松木粉末单一步骤方法。松木木炭用树脂浸渍和随后的碳热还原过程中在1650℃在惰性氩气氛生产重量轻生物形态?-SiC陶瓷具有良好的机械性能和孔隙率。松木的高度各向异性的纤维素结构产生新颖纤维素陶瓷与观和宏观多孔结构pseudomorphous到初始多孔组织骨架。所得木材的显微观察和相鉴别。陶瓷有通过扫描电子显微镜(SEM)和X射线衍射(XRD),分别减肥的在N_2气氛木材和酚醛树脂,通过热重量分析(TGA)研究了在加热过程中被执行的实验结果表明,多孔? - 碳化硅具有拓扑均匀的孔结构,这提供了一种低成本的d环保型路线先进的陶瓷材料,具有近净形状的潜力。

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