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MODELING OF ELECTROCHEMICAL DOUBLE LAYER CAPACITORS BY MEANS OF FRACTIONAL IMPEDANCE

机译:通过分数阻抗建模电化学双层电容器

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The application of the fractional calculus for modeling electrochemical double layer capacitors is a novel way to get simpler and precise models. By means of the method of impedance spectroscopy, experimental results for different values of these have been obtained. In this paper several classical mathematical models are studied and a different method is introduced in order to get a model from electrochemical double layer capacitors. This method is based on distinct models with fractional elements and the fitted of experimental data is realized with few parameters and minimal error. Finally, is proposed a model based in Havriliak-Negami function which achieves an excellent fitted on the over-all frequencies analyzed.
机译:用于建模电化学双层电容器的分数微积分是一种更简单和精确模型的新方法。借助于阻抗光谱法,已经获得了这些不同值的实验结果。在本文中,研究了几种经典的数学模型,并引入了不同的方法,以便从电化学双层电容器获得模型。该方法基于具有分数元件的不同模型,并且使用少数参数和最小误差实现实验数据的安装。最后,提出了一种基于Havriliak-Neg大米函数的模型,该模型实现了在分析的所有频率上拟合的优异。

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