The determination of the relaxation modulus using the step imposition of a strain is an important step in the fitting of the parameters of viscoelastic constitutive equation. In the nonlinear region the true shear strain imposed on a polyethylene melt is found to deviate considerably from the targeted strain due to the presence of wall slip which is documented here. The presence of the wall slip reduces the range of strains for which the strain-dependent relaxation modulus can be determined for the linear polyethylene melt investigated.
展开▼