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Synthesis and Properties of Novel Through-Space Conjugated Polymer with 2.2Paracyclophane and Ferrocene in the Main Chain

机译:具有2.2截晶烷和主要链中的新型通过空间缀合聚合物的合成与性能和主链中的二茂铁

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摘要

Novel conjugated polymer which has alternating [2.2]paracyclophane and ferrocene units in the polymer backbone was synthesized by palladium-catalyzed polycondensation.The polymer showed delocalization of the pi-electron via the through-space of the [2.2]paracyclophane moiety.Electrochemical behaviors of this polymer were also investigated in detail.
机译:通过钯催化的缩聚合成了具有交替[2.2]截晶烷的新型共轭聚合物和聚合物主链中的二茂铁单元。聚合物通过[2.2]截谱部分的通孔,通过空间显示了PI-电子的分层化。电化学行为还详细研究了该聚合物。

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