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Decomposition of acetaldehyde in atmospheric pressure filamentary nitrogen plasma

机译:在大气压丝氮等离子体中分解乙醛

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The decomposition of acetaldehyde, for a molecule concentration equal to 500 ppm, is studied in N_2/CH_3CHO mixtures at atmospheric pressure and ambient temperature, energised by a dielectric barrier discharge producing non-homogeneous filamentary plasma. The removal of CH_3CHO is followed by gas chromatography techniques and FTIR spectroscopy. By-products are fully characterized as function of the specific deposited energy. It is shown that CH_3CHO is efficiently decomposed through either electronic collisions or quenching of the nitrogen metastable states. This decomposition leads to various compounds. Main ones are hydrogen, methane, and carbon monoxide, highlighting the break of the C-C bond to produce methyl and formyl radicals. Other minor products are HCN and various nitriles, ethane, isocyanic acid, and acetone.
机译:在大气压和环境温度下在N_2 / CH_3CHO混合物中研究了等于500ppm的分子浓度的乙醛的分解,通过介电阻挡放电产生非均匀丝等离子体的介电阻挡放电通电。除去CH_3CHO之后是气相色谱技术和FTIR光谱。副产品完全表征为特定沉积能量的功能。结果表明,CH_3CHO通过氮稳态状态的电子碰撞或淬火有效地分解。该分解导致各种化合物。主要是氢,甲烷和一氧化碳,突出C-C键的突破以产生甲基和甲酰基。其他次要产品是HCN和各种腈,乙烷,异氰酸和丙酮。

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