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Near-Infrared Photoluminescence of Single-Walled Carbon Nanotubes Obtained by the Pulsed Laser Vaporization Method

机译:通过脉冲激光汽化法获得的单壁碳纳米管的近红外光致发光

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Single-walled carbon nanotubes (SWNTs) with diameters between ~1.1 and ~1.5 nm prepared by the pulsed laser vaporization, dispersed and surfactant-stabilized in D_2O (transparent up to ~1800 nm) show photo- luminescence (PL) from ~1300 up to >1750 nm corresponding to the lowest electronic interband transitions of semiconducting tubes. The characteristic features of this PL such as sharp emission and excitation peaks corresponding to specific (n,m) tubes are similar to those reported recently for SWNTs with smaller diameters around 1 nm. The experimental data are compared with tight-binding model calculations. For the structural assignment of SWNTs we used the empirical relations derived by Bachilo et al.
机译:直径在脉冲激光蒸发,分散和表面活性剂 - 稳定在D_2O(透明高达约1800nm)中,单壁碳纳米管(SWNT)在D_2O(透明至约1800nm)中,显示照片 - 发光(PL)从〜1300升起对应于半导体管的最低电子基带转换的> 1750nm。该PL的特征如诸如特定(n,m)管的急剧发射和激发峰值的特征与最近对于较小直径约为1nm的SWNT的那些相似。将实验数据与紧密结合模型计算进行比较。对于SWNT的结构分配,我们使用了Bachilo等人来源的经验关系。

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