REACTIONS OF ATOMIC CARBON WITH 2-NORBORNENE

摘要

Reaction of atomic carbon with 2-norbornene,l generates octa-3,7-dien-l-yne, 5 in a reaction over bicyclo[3.2.1]octa-2,3-diene, 4 which fragments to 5. 4 has also been trapped by THF. The potential energy surfaces of C_8H_(10) have been evaluated by means of the AM1 semiempirical method.