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Castor, cottonseed, and soybean oil bleaching by activated bentonites

机译:Castor,Cottoneed和Soybean油漂白活性膨润土

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Acid-treated clays are employed industrially as catalysts, catalyst supports and adsorbents. A relatively new market for activated clay is in animal feed where it absorbs mycotoxins. In terms of consumption, the most important use of the activated clays is in the purification, decolorization and stabilization of vegetable oils. They are used to remove phospholipids, soaps, trace metals, organic compounds (for example, chlorophyll) and their degradation products, which impart undesirable colors to the edible oils. The adsorptive capacity of these materials is significantly increased by treatment with strong inorganic acids, particularly sulfuric and hydrochloric acid. In this work, two bentonite clays with different mineralogical compositions from Mendoza, Argentine, were activated with H_2SO_4 solutions of 4 and 8 N at 90 °C for 3.5 hours. These treatment effects under clay structural properties were tested by thermogravimetry, infrared spectrometry and chemical analysis. The activated samples were tested in order to verify their bleaching capacity for castor, cottonseed, and soybean oils and were compared to a standard commercial bleaching clay. Bleaching efficiency was strongly dependent on acid concentration used for clay activation. The treated samples have shown a bleaching capacity compared to the standard. The mineralogical composition of natural clays have has influenced the properties of treated clays (or activated clays) and these properties increased its bleaching capacity.
机译:酸处理过的粘土在工业上用作催化剂,催化剂载体和吸附剂。对活性白土一个相对较新的市场是在动物饲料在那里吸收毒素。在消费方面,活性粘土的最重要的用途是在净化,脱色和植物油的稳定。它们被用于去除磷脂,皂类,微量金属,有机化合物(例如,叶绿素)和它们的降解产物,其赋予不希望的颜色的食用油。这些材料的吸附能力强无机酸,特别是硫酸和盐酸显著增加治疗。在这项工作中,与来自门多萨,阿根廷不同的矿物学组成的两种膨润土,用4 H_2SO_4溶液和8 N在90℃下3.5小时活化。下粘土的结构特性,这些治疗效果通过热重,红外光谱和化学分析测试。激活的样本,以验证蓖麻,棉籽,油和大豆油的脱色能力进行了测试,并进行了比较标准的商业漂白粘土。漂白效率强烈地依赖于用于粘土活化酸浓度。处理过的样品已经显示比标准漂白能力。天然粘土的矿物组成已经影响了处理过的粘土(或活性粘土)的性质和这些特性增加了它的漂白能力。

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