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Comparison of Superconducting Properties of Bulk MgB_2 made by Hot Deformation and High Temperature-High Pressure Sintering

机译:热变形和高温高压烧结制备的块状MGB_2超导性能的比较

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Two different kinds of bulk MgB_2 material were produced by (i) hot deformation of MgB_2 pellets, prepared by the reaction of Mg and B powders, at temperatures around 900 deg C and pressures up to 450 MPa and (ii) by sintering of MgB_2 powder up to 1000 deg C and pressures up to 8 GPa. In both cases the material has full density and sharp superconducting transitions at up to 39 K. The samples were characterized by measurements of x-ray diffraction, ac susceptibility, electrical resistance and magnetization. Material (i) is anisotropic and shows a weak texture verified by x-ray diffraction and the ratio of the upper critical fields H_(c2)~(a,b)/H_(c2)~c approx 1.2. Material (ii) prepared at optimal conditions is macroscopically isotropic and shows improved superconducting parameters including critical current densities of j_c approx 10~5 Acm~2 at 10 K and 1T, upper critical field mu_0H_(c2)(0 K) approx =23 T and irreversibility field mu_0H_(irr)(10 K) approx =12 T. It is shown that the width of the superconducting transition curves of polycrystalline material measured in higher magnetic fields is mainly due to the anisotropy of H_(c2).
机译:通过(i)通过Mg和B粉末的反应制备的MgB_2颗粒的热变形,通过烧结MgB_2粉末,通过(i)由Mg和B粉末的反应制备的MgB_2颗粒的热变形制备的两种不同类型的块状MgB_2材料。高达1000℃并压力高达8 GPa。在这两种情况下,该材料具有全密度和尖锐的超导转变,高达39 K.样品通过测量X射线衍射,交流敏感,电阻和磁化。材料(I)是各向异性的,并且显示通过X射线衍射验证的弱纹理,并且上临界领域H_(C2)〜(A,B)/ H_(C2)〜C的比率约为1.2。在最佳条件下制备的材料(II)是宏观各向同性的,并且显示出改善的超导参数,包括J_C的临界电流密度为10k和1T的临界电流密度,上临界场MU_0H_(C2)(0k)约= 23t和不可逆转的场景MU_0H_(IRR)(10k)约= 12t。示出了在较高磁场中测得的多晶材料的超导转变曲线的宽度主要是由于H_(C2)的各向异性。

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