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Catalytic Reforming of Methane with Carbon Dioxide over Nickel Catalysts under High Pressure

机译:高压下镍催化剂用二氧化碳催化重整

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The production of synthesis gas by CO_2 reforming of CH_4 is one of the attractive routes for the utilization of CH_4 and CO_2 resources. The product mixture from a stoichiometric (1:1) feed has a high CO/H_2 ratio that is suitable for methanol and F-T synthesis. Generally, CH_4 is preserved at high pressure in natural gas fields, and most F-T synthesis and methanol synthesis from CO/H_2 are performed at high pressure. Hence, from an economical point of view the CH_4/CO_2 reforming should be carried out under high pressure. As it is well known that higher pressures favor coking in the CH_4/CO_2 reforming, researches of the reforming reaction under high pressures are required. However, most of the researches were performed at atmospheric pressure, and only a few studies were conducted at high pressures. In this contribution, the behavior of different oxide supported Ni catalysts and the carbon deposition in the reforming of CH_4/CO_2 under high pressure was investigated.
机译:CO_4的CO_4重整的合成气的生产是利用CH_4和CO_2资源的吸引力路线之一。来自化学计量(1:1)进料的产物混合物具有高CO / H_2的比例,适用于甲醇和F-T合成。通常,在天然气场的高压下保留CH_4,并且大多数F-T合成和来自CO / H_2的甲醇合成在高压下进行。因此,从经济的观点来看,CH_4 / CO_2重整应在高压下进行。众所周知,在CH_4 / CO_2重整中较高的压力偏爱焦化,需要在高压下进行重整反应的研究。然而,大多数研究在大气压下进行,并且在高压下仅进行了一些研究。在该贡献中,研究了不同氧化物支持的Ni催化剂的行为和CH_4 / CO_2在高压下的重整中的碳沉积。

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