首页> 外文会议>International SAMPE Symposium and Exhibition >SURFACE MODIFICATION OF POLYIMIDE BY ATMOSPHERIC PRESSURE PLASMA FOR ADHESIVE BONDING WITH TITANIUM AND ITS APPLICATION TO AVIATION AND SPACE
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SURFACE MODIFICATION OF POLYIMIDE BY ATMOSPHERIC PRESSURE PLASMA FOR ADHESIVE BONDING WITH TITANIUM AND ITS APPLICATION TO AVIATION AND SPACE

机译:用钛粘合剂粘合的大气压等离子体的表面改性及其在航空和空间中的应用

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It is noted that in search of long term and efficient service performance in the context of future generation of aerospace materials, there is increasing need of metal-high performance polymer composite. Based on these considerations, high temperature resistant polymeric sheet such as Polyimide Meldin7001 sheet, is joined with Titanium sheet by employing ultra high temperature resistant Polyimide adhesive. In order to increase surface energy of Polyimide surface, atmospheric pressure plasma treatment is used to modify the Polyimide surface. Atmospheric pressure plasma treatment creates physical and chemical changes such as cross linking, formation of free radicals and oxygen functionalization in the form of polar groups on polymer surface resulting in improvement of wetting and adhesion characteristics. Surface of Polyimide (PI) sheet is treated with atmospheric pressure plasma for different exposure periods. Surface energy of PI sheet increases with increase in exposure time. However, after a certain exposure time of plasma, deterioration of surface layer of PI substrate results in degradation and embitterment of PI which is not suitable for adhesive bonding. Optical microscopic, SEM (EDS), analysis of treated and untreated specimen is carried out to examine the surface characteristics. Treated samples and untreated samples of Polyimide are bonded together with overlap joints. Lap shear bond strength of treated and untreated samples was measured by tensile test to study the effect of treatment on adhesive bond strength. The optimized time of plasma treatment suggested in this investigation results in maximum adhesive bond strength and consequently, this technology is highly acceptable for aviation and space applications.
机译:值得注意的是,在未来一代航空航天材料的背景下寻找长期和高效的服务性能,需要越来越需要金属高性能聚合物复合材料。基于这些考虑因素,通过采用超高耐高温聚酰亚胺粘合剂与钛板接合高温耐含摩尔丝体积薄片。为了增加聚酰亚胺表面的表面能,使用大气压等离子体处理来改变聚酰亚胺表面。大气压等离子体处理产生物理和化学变化,例如交叉连接,形成自由基和氧官能化的聚合物表面上的极性基团的形式,从而提高润湿性和粘合特性。聚酰亚胺(PI)片材的表面用大气压等离子体处理,用于不同的暴露时段。 PI板的表面能随着曝光时间的增加而增加。然而,在等离子体的一定曝光时间之后,PI衬底的表面层的劣化导致PI的降解和缓存,其不适合粘合剂粘合。进行光学显微镜,SEM(EDS),进行处理和未处理标本的分析以检查表面特征。处理的样品和未处理的聚酰亚胺样品与重叠接头一起粘合在一起。通过拉伸试验测量处理和未处理样品的圈剪粘合强度,以研究处理对粘合剂强度的影响。在该研究中提出的血浆处理的优化时间导致最大的粘合剂强度,因此,该技术对于航空和空间应用是高度可接受的。

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