Dynamic State Phase Diagrams For Nucleated Systems

摘要

In the present research the topological analysis of nucleation rates surfaces based on the nucleation rate surface and the phase diagram relationship is used. The qualitative relation of phase (stable) state diagram behavior with intermolecular interaction is well known in theory of solutions. The dynamic state phase diagrams are introduced and discussed here. Transformation of these diagrams with deviation of system from equilibrium states is considered. It is found in agreement with results of non-equilibrium thermodynamics, that for system moving away from the equilibrium state the molecules are losing individuality and intermolecular interaction becomes interaction similar to the unimolecular system.