Rh(I)OR as Finely Tunable Base Catalyst

摘要

@@1.Introduction The Bronsted and Lewis bases are one of the benchmark reagents in organic synthesis.We here focused on a finely tunable base catalyst based on transition metal center with various types of ligands.This presentation opens a basic nature of Rh(I)OR complex with suitable ligand.The representative outcome of Rh(I)OMecatalyzed hydration of organonitrile at ambient conditions,Rh(I)OR-catalyzed Aldol-type addition reaction, and Rh(I)OAc-catalyzed rapid hydroboration of vinylarenes are discussed.