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The breakdown mechanism in barium titanate-based ferroelectric ceramics

机译:基于钛酸钡的铁电陶瓷中的击穿机制

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摘要

The breakdown phenomenon and mechanism of BaTiO/sub 3/-CaSnO/sub 3/-CaTiSiO/sub 5/ (BCC) ferroelectric ceramics, which have a special grain-core-grain-shell microstructure, are investigated. The relation of current I vs. electrical intensity E of BCC ferroelectric ceramics is found to exhibit a four-region characteristic. When an electric field weaker than 2 kV/mm is applied (region I), a conduction current of 10/sup -8/ A is obtained. The leakage current then increases linearly with increasing voltage up to 5 kV/mm in an ohmic manner (region II) within 10/sup -6/ A. Region III is a saturation region, in which the current remains constant while the electric field increased to 7 kV/mm. For voltages still higher (region IV), the current begins to rise steeply, resulting in the occurrence of breakdown through weaker zones, until a negative resistance region begins, with the simultaneous destruction of the entire specimen caused by thermal explosion.
机译:研究了BATIO / sub 3 / -casno / sub 3 / -catisio / sub 5 /(bcc)铁电陶瓷的击穿现象和机理,所述铁电陶瓷具有特殊的晶粒晶粒壳微观结构。发现BCC铁电陶瓷的电流I与电强度E的关系表现出四个区域特性。当施加超过2kV / mm的电场(区域I)时,获得10 / sup -8 / a的导通电流。然后,泄漏电流随着在10 / sup -6 / A内的欧姆方式(区域II)内的增加电压,在10 / sop -6 / A内的欧姆方式增加到5kV / mm。区域III是饱和区域,其中电场在电场增加时保持恒定。到7 kV / mm。对于电压仍然较高(区域IV),电流开始陡峭地升高,导致通过较弱的区域发生故障,直到负电阻区域开始,同时破坏由热爆炸引起的整个样本。

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