首页> 外文会议>American Nuclear Society;International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors >INTERFACE CHARACTERIZATION OF CANDIDATE DUAL-PURPOSE BARRIER COATINGS FOR SIC/SIC ACCIDENT TOLERANT FUEL CLADDING
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INTERFACE CHARACTERIZATION OF CANDIDATE DUAL-PURPOSE BARRIER COATINGS FOR SIC/SIC ACCIDENT TOLERANT FUEL CLADDING

机译:SIC / SIC耐高温燃料包壳的双键双壁障壁涂层的界面表征

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SiC/SiC composites have gained significantattention as accident tolerant fuel cladding for their hightemperature mechanical properties and superioroxidation kinetics in accident scenarios. However,operational LWR coolant and irradiation conditionscause issues regarding SiC matrix dissolution and fissionproduct retention respectively. A potential solution is theapplication of a dual-purpose (environmental barrier andhermetic seal) coating. The goal of this research is to aidin the down-selection process in identifying the highestperformance coating for LWR conditions. One of the mostimportant selection criteria is the coating-substratemechanical stability. This research presents aninvestigation of the relationship between fracture strengthand microstructure through small scale mechanicaltesting and TEM analysis. Micro-cantilevers werefabricated across the SiC/coating interfaces on severalcandidates including PVD Cr and CrN. Testing wasperformed at ambient and 320°C. The lower-boundaverage ambient failure strength for the SiC/Cr andSiC/CrN interfaces were on the order of 3.2 Gpa and 3-5Gpa respectively. High temperature tests revealed adramatic reduction in strength, around 0.4GPa. Neutronirradiated SiC/Cr interfaces (~0.5dpa at 330°C) showedslightly reduced failure strength of 2.9 Gpa at ambienttemperature. A TEM investigation compared irradiatedand pristine SiC/Cr interfaces.
机译:SiC / SiC复合材料取得了显著成绩 由于其较高的耐油性而受到关注 温度机械性能优越 事故场景中的氧化动力学。然而, LWR冷却液的运行状况和辐照条件 引起有关SiC基体溶解和裂变的问题 产品保留率。潜在的解决方案是 双重用途(环境屏障和 密封)涂层。这项研究的目的是帮助 在向下选择过程中确定最高 适用于轻水堆条件的高性能涂料。其中最...之一 重要的选择标准是涂料基质 机械稳定性。这项研究提出了 断裂强度之间关系的研究 和通过小规模机械的微观结构 测试和TEM分析。微型悬臂 跨SiC /涂层界面在几个表面上制造 候选物包括PVD Cr和CrN。测试之前 在环境温度和320°C下进行。下界 SiC / Cr的平均环境破坏强度 SiC / CrN界面的数量级为3.2 Gpa和3-5 Gpa分别。高温测试显示 强度显着降低,约为0.4GPa。中子 辐照的SiC / Cr界面(在330°C时约为0.5dpa)显示 在环境温度下略微降低了2.9 Gpa的破坏强度 温度。透射电镜研究比较辐照 和原始的SiC / Cr界面。

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