首页> 外文会议>International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors >INTERFACE CHARACTERIZATION OF CANDIDATE DUAL-PURPOSE BARRIER COATINGS FOR SIC/SIC ACCIDENT TOLERANT FUEL CLADDING
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INTERFACE CHARACTERIZATION OF CANDIDATE DUAL-PURPOSE BARRIER COATINGS FOR SIC/SIC ACCIDENT TOLERANT FUEL CLADDING

机译:SiC / SIC事故耐燃料包层的候选二元屏障涂层的界面表征

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SiC/SiC composites have gained significantattention as accident tolerant fuel cladding for their hightemperature mechanical properties and superioroxidation kinetics in accident scenarios. However,operational LWR coolant and irradiation conditionscause issues regarding SiC matrix dissolution and fissionproduct retention respectively. A potential solution is theapplication of a dual-purpose (environmental barrier andhermetic seal) coating. The goal of this research is to aidin the down-selection process in identifying the highestperformance coating for LWR conditions. One of the mostimportant selection criteria is the coating-substratemechanical stability. This research presents aninvestigation of the relationship between fracture strengthand microstructure through small scale mechanicaltesting and TEM analysis. Micro-cantilevers werefabricated across the SiC/coating interfaces on severalcandidates including PVD Cr and CrN. Testing wasperformed at ambient and 320°C. The lower-boundaverage ambient failure strength for the SiC/Cr andSiC/CrN interfaces were on the order of 3.2 Gpa and 3-5Gpa respectively. High temperature tests revealed adramatic reduction in strength, around 0.4GPa. Neutronirradiated SiC/Cr interfaces (~0.5dpa at 330°C) showedslightly reduced failure strength of 2.9 Gpa at ambienttemperature. A TEM investigation compared irradiatedand pristine SiC/Cr interfaces.
机译:SiC / SiC复合材料已获得显着注意事故耐受燃料包层的高度温度机械性能和优越事故情景中的氧化动力学。然而,操作LWR冷却剂和辐照条件导致关于SIC矩阵溶解和裂变的问题产品保留。潜在的解决方案是应用两用(环境屏障和密封件)涂层。这项研究的目标是援助在识别最高的下选择过程中LWR条件的性能涂层。其中最...之一重要的选择标准是涂层基材机械稳定性。这项研究提出了一个裂缝强度关系的调查通过小规模机械微观结构测试和TEM分析。微悬臂是在几个SiC /涂层界面上制造候选人包括PVD CR和CRN。测试是在环境温度和320°C下进行。下限SiC / Cr的平均环境失效强度SIC / CRN接口约为3.2 GPA和3-5GPA分别。高温测试揭示了一个强度降低,大约0.4GPa。中子辐照的SiC / Cr界面(330°C〜0.5dPa)显示在环境温度下略微降低2.9 gpa的失效强度温度。辐照比较TEM调查和原始SiC / CR接口。

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